Eight-connected coordination framework supported by tricopper(II) secondary building blocks

被引：30

作者：

Lysenko, Andrey B. ^{[1
]}

Govor, Evgen V. ^{[1
]}

Domasevitch, Konstantin V. ^{[1
]}

机构：

[1] Kiev Univ, Inorgan Chem Dept, UA-01033 Kiev, Ukraine

来源：

INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 01期

关键词：

copper; polynuclear complexes; bitriazole; metal-organic frameworks; crystal structures;

D O I：

10.1016/j.ica.2006.08.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In a series of coordination polymers based upon 4,4'-bitriazole (btr) [Cu3Cl2(H2O)(2)(btr)(4)](2)(ZnCl4)(2)(Cl3ZnOZnCl3), [CU3Cl2(H2O)(2)(btr)(4)](MCl4)(2) (M = Cd; Hg), eight-connected metal-organic frameworks related to a CsCl (bcu) structure originate in the functionality of trinuclear copper/chloride ensembles bridged by the organic ligands. [CU3Cl4(btr)(4)]Cl-2 complex adopts simpler 1D polymeric structure also incorporating trinuclear copper/chloride clusters. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：55 / 60

页数：6

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