Characterization of vanadium oxide sol as a starting material for high rate intercalation cathodes

被引:81
作者
Watanabe, T [1 ]
Ikeda, Y [1 ]
Ono, T [1 ]
Hibino, M [1 ]
Hosoda, M [1 ]
Sakai, K [1 ]
Kudo, T [1 ]
机构
[1] Univ Tokyo, Inst Ind Sci, Sakai Lab, Res Ctr Soft Mat Engn, Tokyo 1538505, Japan
关键词
supercapacitors; electrochemical cells; batteries; cathodes; vanadium pentoxidc; V2O5;
D O I
10.1016/S0167-2738(02)00729-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel solution process using vanadium oxide sol with acetone was developed and V2O5/carbon composite cathodes capable of high rate charge/discharge were fabricated. It was found that the sol condition affects the electrochemical performance of the cathodes. This report presents the fabrication process and the electrochemical performance of the cathodes, and the morphological property of the colloidal particle such colloidal particle size, density and shape at various concentrations. The correlation between the electrochemical performance of the cathodes and the colloidal character of the sol is discussed. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:313 / 320
页数:8
相关论文
共 20 条
[1]  
Baes C. F., 1976, HYDROLYSIS CATIONS, pp. 197
[2]  
BERNE BJ, 1976, DYNAMIC LIGHT SCATTE, P53
[3]  
HELLER W, 1980, POLYM COLLOIDS, V2, P153
[4]   PREPARATION AND LITHIUM INTERCALATION OF A NEW VANADIUM-OXIDE WITH A 2-DIMENSIONAL STRUCTURE [J].
HIBINO, M ;
UGAJI, M ;
KISHIMOTO, A ;
KUDO, T .
SOLID STATE IONICS, 1995, 79 :239-244
[5]   DIFFUSE TRANSMISSION SPECTROSCOPY - A STRUCTURAL PROBE OF OPAQUE COLLOIDAL MIXTURES [J].
KAPLAN, PD ;
DINSMORE, AD ;
YODH, AG ;
PINE, DJ .
PHYSICAL REVIEW E, 1994, 50 (06) :4827-4835
[6]  
KOGYO DK, 1999, DENKA BLACK CATALOGU
[7]  
KUDO T, 2001, INT C SOL STAT ION M
[8]  
KUDO T, UNPUB SOLID STATE IO
[9]  
KUDO T, 1996, ELECTROCHEMICAL SOC, P31
[10]  
Kuhn W, 1932, Z PHYS CHEM A-CHEM T, V161, P1