The functionalisation of electron rich aromatic compounds with 1,3-oxazolidines and 1,3-dimethylimidazolidine

被引：32

作者：

Heaney, H

Papageorgiou, G

Wilkins, RF

机构：

[1] Department of Chemistry, Loughborough University, Leicestershire

来源：

TETRAHEDRON | 1997年 / 53卷 / 42期

关键词：

D O I：

10.1016/S0040-4020(97)00922-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-Phenyl- and N-alkyl-oxazolidines react with alkyl chlorosilanes in the presence of electron rich aromatic compounds with the formation of the expected Mannich bases: 2-methoxycarbonyl-3-methyloxazolidine also reacts with 2-methylfuran in the presence of thionyl chloride to give an a-amino acid derivative: the iminium salt derived from 1,3-dimethylimidazolidine was also shown to react with 2-methylfuran. (C) 1997 Elsevier Science Ltd.

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页码：14381 / 14396

页数：16

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