Growth of magnetic carbon with a nanoporous and graphitic structure

被引:20
作者
Sheng, Zhao Min [2 ]
Wang, Jian Nong [1 ]
机构
[1] Tongji Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Adv Civil Engn Mat,Shanghai Key Lab Mat F, Shanghai 200092, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Shanghai Key Lab Laser Proc & Mat Modificat, Shanghai 200240, Peoples R China
基金
中国国家自然科学基金;
关键词
SILICA; NANOPARTICLES; SUPERLATTICES; NANOCRYSTALS; FABRICATION; PYROLYSIS; NANOTUBES; COMPOSITE; SPHERES; SYSTEM;
D O I
10.1016/j.carbon.2009.07.043
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A porous magnetic composite is synthesized in which each magnetic nanoparticle is closely encapsulated by several graphitic layers and the resulting units are embedded in a carbon matrix with a nanoporous and graphitic structure. The experiments involve preparation of an iron-containing carbon precursor by thermal pyrolysis and subsequent heat treatment of the precursor. Both magnetic particles and porous carbon with a graphitic structure are formed at the same time. After the heat treatment, no additional treatment is needed. The prepared sample has a high surface area of 275-395 m(2) g(-1), a high saturation magnetism of 43-65 emu g(-1) and a high coercivity of 370-650 Oe. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3271 / 3279
页数:9
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