Crystallization Behavior of Coordination Polymers. 1. Kinetic and Thermodynamic Features of 1,3-Bis(4-pyridyl)propane/MCI2 Systems

被引：25

作者：

Carlucci, Lucia ^{[2
]}

Ciani, Gianfranco ^{[2
]}

Manuel Garcia-Ruiz, Juan ^{[4
]}

Moret, Massimo ^{[1
]}

Proserpio, Davide M. ^{[2
]}

Rizzato, Silvia ^{[2
,3
]}

机构：

[1] Univ Milano Bicocca, Dipartimento Sci Mat, Via R Cozzi 53, I-20125 Milan, Italy

[2] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, I-20133 Milan, Italy

[3] Univ Milan, Fac Farm, I-20133 Milan, Italy

[4] Univ Granada, CSIC, IACT, Lab Estudios Cristalog, Armilla 18100, Spain

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 12期

关键词：

METAL-ORGANIC FRAMEWORKS; TO-CRYSTAL TRANSFORMATION; LIESEGANG RING FORMATION; GEL ACUPUNCTURE METHOD; HYDROGEN STORAGE; SOLID-STATE; STRUCTURAL DIVERSITY; FLEXIBLE LIGANDS; BUILDING-BLOCKS; ANION-EXCHANGE;

D O I：

10.1021/cg900985w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of one-, two-, and three-dimensional (1D, 2D, and 3D)coordination polymers has been crystallized front solution as well as in gelled media, by controlled reaction of the flexible ligand 1,3-bis(4-pyridyl)propane with MCI2 salts (M = Mn, Fe, Co, Ni, Cu, Cd, Zn). Attention was paid to the role of kinetic and thermodynamic control upon selection of the final products that can be obtained with different optimized crystallization techniques. It is shown that the correct use of crystallization techniques allows timing of the metal to ligand ratio and absolute concentrations and, hence, control of the crystallization of metal-organic frameworks, including their solvent-mediated phase transitions.

引用

页码：5024 / 5034

页数：11

共 95 条

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