In situ chemical synthesis of SnO2-graphene nanocomposite as anode materials for lithium-ion batteries

被引:495
作者
Yao, Jane [1 ]
Shen, Xiaoping [1 ]
Wang, Bei [1 ]
Liu, Huakun [1 ]
Wang, Guoxiu [1 ]
机构
[1] Univ Wollongong, Sch Mechan Mat & Mechatron Engn, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
基金
澳大利亚研究理事会;
关键词
Graphene; SnO2; nanoparticles; Nanocomposite; Anode material; Lithium-ion batteries; STORAGE; NANOSHEETS; REDUCTION; CAPACITY; SHEETS; OXIDE;
D O I
10.1016/j.elecom.2009.07.035
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
An in situ chemical synthesis approach has been developed to prepare SnO2-graphene nanocomposite. Field emission scanning electron microscopy and transmission electron microscopy observation revealed the homogeneous distribution of SnO2 nanoparticles (4-6 nm in size) on graphene matrix. The electrochemical reactivities of the SnO2-graphene nanocomposite as anode material were measured by cyclic voltammetry and galvanostatic charge/discharge cycling. The as-synthesized SnO2-graphene nanocomposite exhibited a reversible lithium storage capacity of 765 mAh/g in the first cycle and an enhanced cyclability, which can be ascribed to 3D architecture of the SnO2-graphene nanocomposite. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1849 / 1852
页数:4
相关论文
共 19 条
[1]   Electronic confinement and coherence in patterned epitaxial graphene [J].
Berger, Claire ;
Song, Zhimin ;
Li, Xuebin ;
Wu, Xiaosong ;
Brown, Nate ;
Naud, Cecile ;
Mayou, Didier ;
Li, Tianbo ;
Hass, Joanna ;
Marchenkov, Atexei N. ;
Conrad, Edward H. ;
First, Phillip N. ;
de Heer, Wait A. .
SCIENCE, 2006, 312 (5777) :1191-1196
[2]   Facile one-pot synthesis of mesoporous SnO2 microspheres via nanoparticles assembly and lithium storage properties [J].
Demir-Cakan, Rezan ;
Hu, Yong-Sheng ;
Antonietti, Markus ;
Maier, Joachim ;
Titirici, Maria-Magdalena .
CHEMISTRY OF MATERIALS, 2008, 20 (04) :1227-1229
[3]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191
[4]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[5]   Tin-based amorphous oxide: A high-capacity lithium-ion-storage material [J].
Idota, Y ;
Kubota, T ;
Matsufuji, A ;
Maekawa, Y ;
Miyasaka, T .
SCIENCE, 1997, 276 (5317) :1395-1397
[6]   Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations [J].
Kovtyukhova, NI ;
Ollivier, PJ ;
Martin, BR ;
Mallouk, TE ;
Chizhik, SA ;
Buzaneva, EV ;
Gorchinskiy, AD .
CHEMISTRY OF MATERIALS, 1999, 11 (03) :771-778
[7]   Decorating graphene sheets with gold nanoparticles [J].
Muszynski, Ryan ;
Seger, Brian ;
Kamat, Prashant V. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (14) :5263-5266
[8]   Two-dimensional gas of massless Dirac fermions in graphene [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Katsnelson, MI ;
Grigorieva, IV ;
Dubonos, SV ;
Firsov, AA .
NATURE, 2005, 438 (7065) :197-200
[9]   Electric field effect in atomically thin carbon films [J].
Novoselov, KS ;
Geim, AK ;
Morozov, SV ;
Jiang, D ;
Zhang, Y ;
Dubonos, SV ;
Grigorieva, IV ;
Firsov, AA .
SCIENCE, 2004, 306 (5696) :666-669
[10]   Enhanced Cyclic Performance and Lithium Storage Capacity of SnO2/Graphene Nanoporous Electrodes with Three-Dimensionally Delaminated Flexible Structure [J].
Paek, Seung-Min ;
Yoo, EunJoo ;
Honma, Itaru .
NANO LETTERS, 2009, 9 (01) :72-75