Molecular engineering of photosensitizers for nanocrystalline solar cells: Synthesis and characterization of Ru dyes based on phosphonated terpyridines

被引：216

作者：

Zakeeruddin, SM

Nazeeruddin, MK

Pechy, P

Rotzinger, FP

HumphryBaker, R

Kalyanasundaram, K

Gratzel, M

Shklover, V

Haibach, T

机构：

[1] SWISS FED INST TECHNOL,INST PHYS CHEM,LAB PHOTON & INTERFACES,CH-1015 LAUSANNE,SWITZERLAND

[2] SWISS FED INST TECHNOL,CRYSTALLOG LAB,CH-8092 ZURICH,SWITZERLAND

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 25期

关键词：

D O I：

10.1021/ic970008i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the results of an investigation on the preparation, spectral, and photoelectrochemical properties of Ru(II)-polypyridyl complexes containing a new phosphonated terpyridine (P-terpy) ligand: [Ru(H2P-terpy)(2)] and [Ru(HP-terpy)(Me(2)bpy)(NCS)]. Resonance Raman spectral and luminescence studies allow probing into the nature of the low-energy MLCT transitions observed in these complexes. The crystal and molecular structure of the mixed-ligand complex [Ru(HP-terpy)(Me(2)bpy)(NCS)] based on X-ray diffraction study is reported. This complex appears to be a promising candidate as a photosensitizer in dye-sensitized photoelectrochemical cells based on nanocrystalline films of TiO2.

引用

页码：5937 / 5946

页数：10

共 58 条

[1] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].