Palladium-catalyzed kinetic resolution of racemic cyclic and acyclic allylic carbonates with sulfur nucleophiles

被引：57

作者：

Gais, HJ ^{[1
]}

Spalthoff, N ^{[1
]}

Jagusch, T ^{[1
]}

Frank, M ^{[1
]}

Raabe, G ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(00)00523-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A chiral Pd(0) complex bearing the Trost ligand in combination with S-nucleophiles effects the kinetic resolution of cyclic and acyclic allylic carbonates with excellent levels of enantioselectivity to give enantiomerically highly enriched allylic carbonates as well as allylic sulfones and sulfides. This method allows also for a new access to enantiopure cyclic allylic alcohols. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：3809 / 3812

页数：4

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