Determination of the 85Rb ng-series quantum defect by electric-field-induced resonant energy transfer between cold Rydberg atoms

Resonant energy transfer between cold Rydberg atoms was used to determine Rydberg atom energy levels, at precisions approaching those obtainable in microwave spectroscopy. Laser cooled Rb-85 atoms from a magneto-optical trap were optically excited to 32d(5/2) Rydberg states. The two-atom process 32d(5/2)+32d(5/2)-> 34p(3/2)+30g is resonant at an electric field of approximately 0.3 V/cm. This process is driven by the electric dipole-dipole interaction, which is allowed due to the partial f character that the g state acquires in an electric field. The experimentally observed resonant field, together with the Stark map calculation is used to make a determination of the Rb-85 ng-series quantum defect delta(g)(n=30)=0.00405(6).