Facile synthesis of a chiral ionic liquid derived from 1-phenylethylamine

被引：7

作者：

Ashraf, Syed A. ^{[1
]}

Pornputtkul, Yingpit ^{[1
]}

Kane-Maguire, Leon A. P. ^{[1
]}

Wallace, Gordon G. ^{[1
]}

机构：

[1] Univ Wollongong, Intelligent Polymer Res Inst, ARC Ctr Nanostruct Electromat, Wollongong, NSW 2522, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 2007年 / 60卷 / 01期

关键词：

D O I：

10.1071/CH06384

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple route is described to enantiomerically pure ionic liquids derived from (+)- and (-)-1-phenylethylamine. These very low melting point (-42 degrees C) ionic liquids, containing the bis(trifluoromethylsulfonylimide) anion, possess a wide electrochemical potential window between -2.0 and +2.0V (versus Ag|AgCl). They show chiral discrimination between the enantiomeric forms of Mosher's salt, suggesting their potential as media for electrochemical asymmetric syntheses or chiral chromatography.

引用

页码：64 / 67

页数：4

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