Coordination compounds containing urea as precursors for oxides -: A new route of obtaining nanosized CoFe2O4

被引:36
作者
Carp, O.
Patron, L.
Reller, A.
机构
[1] Inst Phys Chem IG Murgulescu Spl, Bucharest, Romania
[2] Univ Augsburg, Solid State Chem, D-86159 Augsburg, Germany
关键词
nanosized materials; magnetic materials; powder diffraction; Mossbauer spectroscopy; CoFe2O4;
D O I
10.1016/j.matchemphys.2006.03.002
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Pure CoFe2O4 particles with an average size in the range 38-57 angstrom and a surface area of 60-67 m(2) g(-1) have been produced at a low temperature (450 degrees C) through thermal decomposition of polynuclear coordination compounds containing urea as ligand, with different metal:ligand molar ratios (Fe3+:Co2+:urea = 2:1:6 and 2:1:8), synthesized by two routes (a precipative and a solid state one). (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:142 / 147
页数:6
相关论文
共 53 条
[1]   MAGNETIC RECORDING MATERIALS SINCE 1975 [J].
BATE, G .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1991, 100 (1-3) :413-424
[2]  
BERA P, 2001, J MATER CHEM, V11, P3215
[3]   Magnetic properties of nanophase CoFe2O4 particles [J].
Blaskov, V ;
Petkov, V ;
Rusanov, V ;
Martinez, LM ;
Martinez, B ;
Munoz, JS ;
Mikhov, M .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1996, 162 (2-3) :331-337
[4]   PREPARATION, BULK CHARACTERIZATION AND SURFACE-CHEMISTRY OF HIGH-SURFACE-AREA COBALT ALUMINATE [J].
BUSCA, G ;
LORENZELLI, V ;
BOLIS, V .
MATERIALS CHEMISTRY AND PHYSICS, 1992, 31 (03) :221-228
[5]   PREPARATION, SOLID-STATE CHARACTERIZATION, AND SURFACE-CHEMISTRY OF HIGH SURFACE-AREA NIXAL2-2XO3-2X MIXED OXIDES [J].
BUSCA, G ;
LORENZELLI, V ;
ESCRIBANO, VS .
CHEMISTRY OF MATERIALS, 1992, 4 (03) :595-605
[6]   Thermal behavior of the coordination compound [Co(urea)6](NO3) [J].
Carp, O ;
Patron, L ;
Reller, A .
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2003, 73 (03) :867-876
[7]   Thermal decomposition study of the coordination compound [Fe(urea)6](NO3)3 [J].
Carp, O ;
Patron, L ;
Diamandescu, L ;
Reller, A .
THERMOCHIMICA ACTA, 2002, 390 (1-2) :169-177
[8]  
CARP O, IN PRESS J THERM ANA
[9]   Reducing gas-sensing properties of ferrite compounds MFe2O4 (M = Cu, Zn, Cd and Mg) [J].
Chen, NS ;
Yang, XJ ;
Liu, ES ;
Huang, JL .
SENSORS AND ACTUATORS B-CHEMICAL, 2000, 66 (1-3) :178-180
[10]  
Chu XF, 1999, SENSOR ACTUAT B-CHEM, V61, P19, DOI 10.1016/S0925-4005(99)00033-7