Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules

被引：459

作者：

Chen, Banglin ^{[1
]}

Ma, Shengqian

Zapata, Fatima

Fronczek, Frank R.

Lobkovsky, Emil B.

Zhou, Hong-Cai

机构：

[1] Univ Texas, Dept Chem, Edinburg, TX 78541 USA

[2] Miami Univ, Dept Chem & Biochem, Oxford, OH 45056 USA

[3] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

[4] Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 04期

关键词：

D O I：

10.1021/ic0616434

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A microporous metal-organic framework, MOF, Cu(FMA)(4,4'-Bpe)(0.5) (3a, FMA = fumarate; 4,4'-Bpe = 4,4'-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.6 A, which are interconnected by pore windows of 2.0 x 3.2 A, 3a shows highly selective sorption behaviors of gas molecules.

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页码：1233 / 1236

页数：4

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