Glucosylated tris-bipyridine ferrous complexes: Construction of hexavalent saccharide clusteres via self-assembly and their recognition by lectin

被引：12

作者：

Hasegawa, T

Matsuura, K

Kobayashi, K ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design, Chikusa Ku, Nagoya, Aichi 4648603, Japan

[2] Nagoya Univ, Grad Sch Engn, Dept Biotechnol, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

CHEMISTRY LETTERS | 2000年 / 05期

关键词：

D O I：

10.1246/cl.2000.466

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hexavalent glycoconjugates were prepared via self-assembly of divalent glycosylated 2,2'-bipyridine derivatives with ferrous chloride. The Lambda- and Delta-stereoisomeric complexes were preferentially formed from alpha- and beta-glucoside derivatives, respectively. The alpha-glucoside cluster exhibited an enhanced affinity for concanavalin A.

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页码：466 / 467

页数：2

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