A novel catalyst for the Knoevenagel condensation of aldehydes with malononitrile and ethyl cyanoacetate under solvent free conditions

被引：136

作者：

Gawande, Manoj B. ^{[1
]}

Jayaram, Radha V. ^{[1
]}

机构：

[1] Univ Bombay, Inst Chem Technol, Dept Chem, Bombay 400019, Maharashtra, India

来源：

CATALYSIS COMMUNICATIONS | 2006年 / 7卷 / 12期

关键词：

MgO/ZrO; solid base catalyst; Knoevenagel condensation; active methylene groups; solvent free;

D O I：

10.1016/j.catcom.2006.03.008

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel, efficient and eco-friendly MgO/ZrO2 catalyst is put forward for the Knoevenagel condensation. The as synthesized catalyst MgO/ZrO2 was characterized by elemental analysis, XRD, FTIR, particle size, SEM-EDXS, average pore diameter, BET surface area analysis, and thermal gravimetric analysis. The Knoevenagel condensation of several aldehydes with ethyl cyanoacetate and malononitrile was carried out at 60 degrees C on MgO/ZrO2 catalyst in the absence of solvent. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：931 / 935

页数：5

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