Correlated structural and optical investigation of terbium-doped zinc oxide nanocrystals

被引:59
作者
Liu, SM [1 ]
Liu, FQ
Guo, HQ
Zhang, ZH
Wang, ZG
机构
[1] Chinese Acad Sci, Inst Semicond, Lab Semicond Mat Sci, Beijing 100083, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China
关键词
nanocrystals; zinc oxide; terbium; photoluminescence;
D O I
10.1016/S0375-9601(00)00341-8
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Tb3+-doped zinc oxide nanocrystals with a hexagonal wurzite structure were successfully prepared by reaction between Zn-O-Tb precursors and LiOH in ethanol. Good incorporation of Tb3+ in ZnO nanocrystals is proved by XRD, FTIR, PL and PLE measurements. The presence of acetate complexes to zinc atoms on particle surfaces is disclosed by FTIR results. Emission from both Tb3+ ions and surface states in ZnO matrix, as well as their correlation were observed. The luminescence mechanism is discussed. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:128 / 133
页数:6
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