Preparation and investigation of nanostructured SiC-nickel layers by electrodeposition

被引:105
作者
Benea, L
Bonora, PL
Borello, A
Martelli, S
Wenger, F
Ponthiaux, P
Galland, J
机构
[1] Ecole Cent Paris, Lab CFH, F-92295 Chatenay Malabry, France
[2] ENEA, CR Frascati, Div Fis Applicata, Rome, Italy
[3] ENEA, CR Frascati, Div Nuovi Mat, Rome, Italy
[4] Dunarea de Jos Univ Galati, Dept Met & Mat Sci, Galati 6200, Romania
[5] Univ Trent, Dept Mat Engn, I-38050 Trento, Italy
关键词
nanostructured layers; nanoparticles; silicon carbide; nickel matrix; electrodeposition;
D O I
10.1016/S0167-2738(02)00586-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Nanocomposite layers have been obtained by electrochemical deposition of silicon carbide nanoparticles (mean diameter 20 nm) in a nickel plating bath. The influence of nanoparticles on nickel electroplating is studied by electrochemical impedance spectroscopy (EIS) at cathodic potential. Cathodic polarization diagrams have been determined in the electrolyte with and without nanoparticles. We show that incorporation of 20 nm SiC particles into nickel deposition modifies the impedance and cathodic polarization diagrams in correlation with the modification of the surface morphology and crystallinity of nickel matrix. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:89 / 95
页数:7
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