Synthesis and X-ray structures of octanuclear silver(I) cluster [Ag8(μ6-S){S2P(OC2H5)2}6] and its copper(I) analogue [Cu8(μ8-S){S2P(OC2H5)2}6]

被引：46

作者：

Matsumoto, K ^{[1
]}

Tanaka, R

Shimomura, R

Nakao, Y

机构：

[1] Osaka City Univ, Fac Sci, Dept Chem, Sumiyoshi Ku, Osaka 5588585, Japan

[2] Osaka City Univ, Fac Engn, Sumiyoshi Ku, Osaka 5588585, Japan

[3] Okayama Univ, Fac Educ, Okayama 7008530, Japan

来源：

INORGANICA CHIMICA ACTA | 2000年 / 304卷 / 02期

关键词：

silver complexes; copper complexes; dithiophosphate complexes; crystal structures; cluster complexes;

D O I：

10.1016/S0020-1693(00)00084-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The octanuclear cluster of silver(I) [Ag-8(mu(6)-S){S2P(OC2H5)(2)}(6)] comprises eight Ag atoms located at the corners of a cube elongated along the threefold axis with a mu(6)-S atom in its center and each sulfur atom of the S2P(OC2H5)(2)(-) ligand bridges two opposite sides of a cubic face formed by four Ag atoms. An infinite arrangement of {[Ag-8(mu(6)-S){S2P(OC2H5)(2)}(6)]. H2O}(infinity) is formed along the c-axis. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：293 / 296

页数：4

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