Expanding the scope of transformations of organoboron species: carbon-carbon bond formation with retention of configuration

被引：127

作者：

Crudden, Cathleen M. ^{[1
]}

Glasspoole, Ben W. ^{[1
]}

Lata, Christopher J. ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 44期

关键词：

CROSS-COUPLING REACTIONS; CATALYTIC ASYMMETRIC HYDROBORATION; SECONDARY ALKYL-HALIDES; ELECTRON-DEFICIENT OLEFINS; AMINO-ACID DERIVATIVES; HALO BORONIC ESTERS; ARYLBORONIC ACIDS; ROOM-TEMPERATURE; ENANTIOSELECTIVE SYNTHESIS; RHODIUM COMPLEXES;

D O I：

10.1039/b911537d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of boron chemistry for the synthesis of enantiomerically enriched organic compounds is described. Key advances towards the preparation of organoboranes with control of stereochemistry are supplemented by a discussion of the use of these chiral organoboranes in carbon-carbon bond forming reactions. Particular emphasis is given to advances in the Suzuki-Miyaura coupling of chiral secondary organoboranes and homologation reactions. Both of these reactions convert the initially generated B-C bond into a C-C bond and thus lead to a significant increase in complexity.

引用

页码：6704 / 6716

页数：13

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