Influence of subsurface, charged impurities on the adsorption of chlorine at TiO2(110)

被引：21

作者：

Batzill, M ^{[1
]}

Hebenstreit, ELD ^{[1
]}

Hebenstreit, W ^{[1
]}

Diebold, U ^{[1
]}

机构：

[1] Tulane Univ, Dept Phys, New Orleans, LA 70118 USA

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 367卷 / 3-4期

基金：

美国国家科学基金会; 美国国家航空航天局;

关键词：

D O I：

10.1016/S0009-2614(02)01635-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adsorption of chlorine on TiO2(110) surfaces modified by subsurface impurity atoms was studied by scanning tunneling microscopy. Adsorption was found to be suppressed in the vicinity of positively charged subsurface donor atoms. The reduced adsorption is explained by an increased electron affinity close to the impurity atoms that renders these sites energetically unfavorable for acceptor-like adsorbates. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：319 / 323

页数：5

共 15 条

[1]

BATZILL M, IN PRESS PHYS REV B

[2] THE ROLE OF METAL-ION DOPANTS IN QUANTUM-SIZED TIO2 - CORRELATION BETWEEN PHOTOREACTIVITY AND CHARGE-CARRIER RECOMBINATION DYNAMICS [J].