Zeolite-like copper iodide framework with new 66 topology

被引：110

作者：

Bi, Minghui ^{[1
]}

Li, Guanghua ^{[1
]}

Zou, Yongchun ^{[1
]}

Shi, Zhan ^{[1
]}

Feng, Shouhua ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 03期

关键词：

D O I：

10.1021/ic061163c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have described an unprecedented three-dimensional zeolite-like copper iodide constructed from Cu4I4(DABCO)(4) (DABCO = 1,4-diazabicyclo[2.2.2]octane) supertetrahedron units. This compound forms a four-connected network with new 6(6) topology. Its structure reveals one-dimensional channels along the [001] direction, and the framework displays interesting self-penetration. The title compound shows photoluminescence at room temperature in the solid state.

引用

页码：604 / 606

页数：3

共 27 条

[1]

Abrahams BF, 1999, ANGEW CHEM INT EDIT, V38, P1475, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1475::AID-ANIE1475>3.0.CO

[2]

2-3

[3]

Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO

[4]

2-Z