Effect of HZSM-5 zeolite addition to a fluid catalytic cracking catalyst.: Study in a laboratory reactor operating under industrial conditions

被引：64

作者：

Arandes, JM ^{[1
]}

Abajo, I ^{[1
]}

Fernández, I ^{[1
]}

Azkoiti, MJ ^{[1
]}

Bilbao, J ^{[1
]}

机构：

[1] Univ Basque Country, Dept Ingn Quim, E-48080 Bilbao, Spain

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2000年 / 39卷 / 06期

关键词：

D O I：

10.1021/ie990335t

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The kinetic behavior has been studied for cracking a commercial feedstock on a hybrid catalyst (with 5 wt % of HZSM-5 zeolite) made up of 80 wt % of a catalyst equilibrated in a fluid catalytic cracking (FCC) unit and of 20 wt % of a catalyst prepared based on a HZSM-5 zeolite. A laboratory-scale reactor which allows for operation under conditions similar to those of commercial FCC units has been used. From the analysis of the gases and gasoline obtained in the 500-550 degrees C range, with contact times between 2 and 10 s and for a catalyst/feedstock = 6, the influence of HZSM-5 zeolite presence in the catalyst on gas and gasoline composition and on gasoline research octane number has been analyzed.

引用

页码：1917 / 1924

页数：8

共 25 条

[1] EFFECTS OF HIGH-LEVEL ADDITIONS OF ZSM-5 TO A FLUID CATALYTIC CRACKING (FCC) RE-USY CATALYST [J].

ADEWUYI, YG ;

KLOCKE, DJ ;

BUCHANAN, JS .

APPLIED CATALYSIS A-GENERAL, 1995, 131 (01) :121-133

[2] Compositional changes in FCC gasoline products resulting from high-level additions of ZSM-5 zeolite to RE-USY catalyst [J].

Adewuyi, YG .

APPLIED CATALYSIS A-GENERAL, 1997, 163 (1-2) :15-29

[3] Activity and selectivity of fluidized catalytic cracking catalysts in a riser simulator: The role of Y-zeolite crystal size [J].

Al-Khattaf, S ;

de Lasa, H .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1999, 38 (04) :1350-1356

[4]

ANDERSON PC, 1972, J I PETROL, V58, P83

[5]

Argauer R.J., 1972, US Pat., Patent No. [3702886, US3702886A]

[6]

BERTY JM, 1974, CHEM ENG PROG, V70, P78

[7] OCTANE ENHANCEMENT IN FLUID CATALYTIC CRACKING .1. ROLE OF ZSM-5 ADDITION AND REACTOR TEMPERATURE [J].

BISWAS, J ;

MAXWELL, IE .

APPLIED CATALYSIS, 1990, 58 (01) :1-18

[8]

Buchanan JS, 1996, APPL CATAL A-GEN, V134, P247

[9] REACTIONS OF MODEL COMPOUNDS OVER STEAMED ZSM-5 AT SIMULATED FCC REACTION CONDITIONS [J].

BUCHANAN, JS .

APPLIED CATALYSIS, 1991, 74 (01) :83-94

[10]

Chen N.Y., 1973, US Patent, Patent No. 4112056

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