Chromium arene complexes in synthesis of trans-resveratrol

被引：10

作者：

Polunin, KE

Schmalz, HG

Polunina, LA

机构：

[1] Russian Acad Sci, Inst Phys Chem, Moscow 119991, Russia

[2] Tech Univ Berlin, Inst Organ Chem, D-10623 Berlin, Germany

来源：

RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 07期

关键词：

chromium(0) eta(6)-arenetricarbonyl complex; trans-resveratrol; phytoalexin; hydroxystilbenes; methoxystilbenes; aldol condensation; Wittig-Horner reaction; demethylation;

D O I：

10.1023/A:1020921101384

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Two variants of synthesis of resveratrol (3,5,4'-trans-trihydroxystilbene) from dimethyl ether and anisaidehyde were performed using the chromium eta(6)-benzenetricarbonyl complex. The Wittig-Horner reactions or aldol condensation in four stages followed by demethylation by EtSLi were applied.

引用

页码：1319 / 1324

页数：6

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