Experimental determination of the fate of rising CO2 droplets in seawater

Direct oceanic disposal of fossil fuel CO2 is being considered as a possible means to moderate the growth rate of CO2 in the atmosphere. We have measured the rise rate and dissolution rate of freely released CO2 droplets in the open ocean to provide fundamental data for carbon sequestration options. A small amount of liquid CO2 was released at 800 m, at 4.4 degreesC, and the rising droplet stream was imaged with a HDTV camera carried on a remotely operated vehicle. The initial rise rate for 0.9-cm diameter droplets was 10 cm/s at 800 m, and the dissolution rate was 3.0 mumol cm(-2) s(-1). While visual contact was maintained for I h and over a 400 m ascent, 90% of the mass loss occurred within 30 min over a 200 m ascent above the release point. Images of droplets crossing the liquid-gasphase boundary showed formation of a gas head, pinching off of a liquid tail, and rapid gas bubble separation and dissolution.