Supramolecular assemblies based on cucurbituril adducts of hydrogen-bonded molybdenum and tungsten incomplete cuboidal aqua complexes

被引:59
作者
Fedin, VP
Virovets, AV
Sokolov, MN
Dybtsev, DN
Gerasko, OA
Clegg, W
机构
[1] Russian Acad Sci, Inst Inorgan Chem, Novosibirsk 630090, Russia
[2] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
关键词
D O I
10.1021/ic000026r
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Six cis coordinated H2O molecules of the triangular cluster complexes M-3(mu(3)-S)((mu(2)-S)(3)(H2O)(9)](4+) Mo, W) (hydrogen bond donors) complementary to six portal oxygen atoms of cucurbituril (acceptors). The shape and symmetry of the building blocks induce specific crystal structures.
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页码:2227 / +
页数:5
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