Morphological behavior for micelle from polystyrene-b-poly [2-(β-D-glucopyranosyloxy)ethyl acrylate] upon changing the copolymer concentration

被引:17
作者
Liang, YZ [1 ]
Li, ZC [1 ]
Li, FM [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, Dept Polymer Sci & Engn, Beijing 100871, Peoples R China
关键词
D O I
10.1246/cl.2000.320
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multiple morphologies of molecular assemblies of polystyrene-b-poly[2-(beta-D-glucopyranosyloxy)ethyl acrylate] (PSt-b-PGEA) were obtained by initially dissolving it in DMF and then adding water to the organic solution. With increasing the initial copolymer concentration (ICC) from 0.1 wt% to 2.0 wt% in DMF, the molecular assemblies of PSt(77)-b-PGEA(6) were transformed from spheres, to rods, to vesicles, to tubules, and again to vesicles. Concanavalin (Con A) was used to characterize the surface properties of the resulting aggregates.
引用
收藏
页码:320 / 321
页数:2
相关论文
共 17 条
[1]   GLOBULAR CARBOHYDRATE MACROMOLECULE SUGAR BALLS .1. SYNTHESIS OF NOVEL SUGAR-PERSUBSTITUTED POLY(AMIDO AMINE) DENDRIMERS [J].
AOI, K ;
ITOH, K ;
OKADA, M .
MACROMOLECULES, 1995, 28 (15) :5391-5393
[2]  
HALPERIN A, 1992, ADV POLYM SCI, V100, P31
[3]   A new type of artificial glycoconjugate polymer: A convenient synthesis and its interaction with lectins [J].
Kobayashi, K ;
Tsuchida, A ;
Usui, T ;
Akaike, T .
MACROMOLECULES, 1997, 30 (07) :2016-2020
[4]   Multiple morphologies of aggregates from block copolymers containing glycopolymer segments [J].
Li, ZC ;
Liang, YZ ;
Li, FM .
CHEMICAL COMMUNICATIONS, 1999, (16) :1557-1558
[5]  
Miyamoto T, 1999, CHINESE J POLYM SCI, V17, P21
[6]  
Ohno K, 1999, MACROMOL CHEM PHYSIC, V200, P1619, DOI 10.1002/(SICI)1521-3935(19990701)200:7<1619::AID-MACP1619>3.0.CO
[7]  
2-1
[8]   Synthesis and biological properties of mannosylated starburst poly(amidoamine) dendrimers [J].
Page, D ;
Roy, R .
BIOCONJUGATE CHEMISTRY, 1997, 8 (05) :714-723
[9]   Multiple pH-induced morphological changes in aggregates of polystyrene-block-poly(4-vinylpyridine) in DMF/H2O mixtures [J].
Shen, HW ;
Zhang, LF ;
Eisenberg, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) :2728-2740
[10]   Disklike assemblies of a synthetic glycolipid and their association with Concanavalin A [J].
Takeoka, S ;
Sou, K ;
Ohgushi, T ;
Tsuchida, E .
SUPRAMOLECULAR SCIENCE, 1998, 5 (1-2) :159-162