Amidoalane, amidogallane and amidoindane, H2MNH2 (M = Al, Ga or In):: a matrix study of three prototypal molecules with the potential for M-N multiple bonding

被引：27

作者：

Himmel, HJ ^{[1
]}

Downs, AJ ^{[1
]}

Greene, TM ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 10期

关键词：

D O I：

10.1039/b001652g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of Al, Ga or In atoms (M) isolated in NH3-doped Ar matrices gives first the divalent amido derivative HMNH2 (lambda = 436 nm) and then the univalent and trivalent amido derivatives MNH2 and H2MNH2 (lambda = 200-800 nm); the measured and calculated properties of H2MNH2 are outlined.

引用

页码：871 / 872

页数：2

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