Optimal control of a molecular cis-trans isomerization model

被引：27

作者：

Grossmann, F ^{[1
]}

Feng, L ^{[1
]}

Schmidt, G ^{[1
]}

Kunert, T ^{[1
]}

Schmidt, R ^{[1
]}

机构：

[1] Tech Univ Dresden, Inst Theoret Phys, D-01062 Dresden, Germany

来源：

EUROPHYSICS LETTERS | 2002年 / 60卷 / 02期

关键词：

D O I：

10.1209/epl/i2002-00339-6

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The dynamics of a laser-driven nuclear wave packet on two coupled potential energy surfaces with 2 degrees of freedom, modeling the torsion of a C-C double bond interacting with a vibrational mode, is studied by numerically solving the time-dependent Schrodinger equation. An optimal control scheme is employed to determine the laser field to realize a nano-switch for cis-trans isomerization. The basic mechanism of the controlled isomerization process as well as the features of the optimal laser field and its dependence on the final time chosen for the optimization are studied in detail.

引用

页码：201 / 206

页数：6

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