Effect of diffusion-layer morphology on the performance of polymer electrolyte fuel cells operating at atmospheric pressure

被引:127
作者
Jordan, LR
Shukla, AK
Behrsing, T
Avery, NR
Muddle, BC
Forsyth, M [1 ]
机构
[1] Monash Univ, Dept Mat Engn, Clayton, Vic 3168, Australia
[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[3] CSIRO, Mfg Sci & Technol, Clayton, Vic 3169, Australia
关键词
carbon black; gas diffusion electrodes; polymer electrolyte fuel cell;
D O I
10.1023/A:1004088402496
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In general, the performance of polymer electrolyte fuel cells (PEFCs) containing membrane electrode assemblies (MEAs) with diffusion layers of Acetylene Black carbon are superior to those with Vulcan XC-72R carbon. It is suggested that the mechanism of improved performance is that lower porosity Acetylene Black is better at removing water from the MEA, thereby leading to improved gas diffusion. It appears that the diffusion layer plays a seminal role in the water management of the cell as well as in the humidification of the membrane electrolyte.
引用
收藏
页码:641 / 646
页数:6
相关论文
共 21 条
[1]   Influence of Nafion loading in the catalyst layer of gas-diffusion electrodes for PEFC [J].
Antolini, E ;
Giorgi, L ;
Pozio, A ;
Passalacqua, E .
JOURNAL OF POWER SOURCES, 1999, 77 (02) :136-142
[2]  
FERRIERA AC, 1992, ELECTROCHEMICAL SOC, V921, P8
[3]   Influence of the PTFE content in the diffusion layer of low-Pt loading electrodes for polymer electrolyte fuel cells [J].
Giorgi, L ;
Antolini, E ;
Pozio, A ;
Passalacqua, E .
ELECTROCHIMICA ACTA, 1998, 43 (24) :3675-3680
[4]  
HIRSCHENHOFER JH, 1994, FUEL CELL HDB, P6
[5]  
Hoogers G, 1998, PHYS WORLD, V11, P31
[6]  
Kinoshita K., 1988, CARBON ELECTROCHEMIC
[7]   INSITU ELECTRODE FORMATION ON A NAFION MEMBRANE BY CHEMICAL PLATINIZATION [J].
LIU, R ;
HER, WH ;
FEDKIW, PS .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (01) :15-23
[8]  
Paganin VA, 1996, J APPL ELECTROCHEM, V26, P297, DOI 10.1007/BF00242099
[9]  
PARTIER JA, 1994, J ELECTROCHEM SOC, V141, P425
[10]   NAFION DISTRIBUTION IN GAS-DIFFUSION ELECTRODES FOR SOLID-POLYMER-ELECTROLYTE-FUEL-CELL APPLICATIONS [J].
POLTARZEWSKI, Z ;
STAITI, P ;
ALDERUCCI, V ;
WIECZOREK, W ;
GIORDANO, N .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (03) :761-765