Lithium ion transfer at carbon thin film electrode/electrolyte interface

被引：8

作者：

Abe, T

Yamate, S

Iriyama, Y

Inaba, M

Ogumi, Z

Fukutsuka, T

机构：

[1] Kyoto Univ, Grad Sch Engn, Sakyo Ku, Kyoto 6068501, Japan

[2] Himeji Inst Technol, Fac Engn, Himeji, Hyogo 6712201, Japan

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2002年 / 388卷

关键词：

carbon; thin film; lithium ion battery; ion transfer; charge transfer;

D O I：

10.1080/10587250290114005

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lithium ion transfer at an interface between carbonaceous thin film electrode prepared by plasma-assisted chemical vapor deposition and electrolyte was studied by AC impedance spectroscopy. In Nyquist plots, semi-circles assigned as charge (Li+) transfer resistance were observed. The charge transfer resistance was dependent on the electrode potentials. Activation energy for the lithium ion transfer through the interface between electrode and electrolyte was also evaluated.

引用

页码：555 / 560

页数：6

共 15 条

[1] Abe T, 1999, CARBON, V37, P1165
[2] Electrochemical properties of carbonaceous thin films prepared by plasma chemical vapor deposition
Fukutsuka, T
Abe, T
Inaba, M
Ogumi, Z
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (11) : A1260 - A1265
[3] Electrochemical intercalation of Li into carbon thin films prepared by plasma CVD
Fukutsuka, T
Abe, T
Inaba, M
Ogumi, Z
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2000, 340 : 517 - 522
[4] FUKUTSUKA T, 1999, TANSO, V190, P252
[5] APPLICATION OF AC TECHNIQUES TO THE STUDY OF LITHIUM DIFFUSION IN TUNGSTEN TRIOXIDE THIN-FILMS
HO, C
RAISTRICK, ID
HUGGINS, RA
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (02) : 343 - 350
[6] HIGH IONIC-CONDUCTIVITY IN LITHIUM LANTHANUM TITANATE
INAGUMA, Y
CHEN, LQ
ITOH, M
NAKAMURA, T
UCHIDA, T
IKUTA, H
WAKIHARA, M
[J]. SOLID STATE COMMUNICATIONS, 1993, 86 (10) : 689 - 693
[7] Preparation of c-axis oriented thin films of LiCoO2 by pulsed laser deposition and their electrochemical properties
Iriyama, Y
Inaba, M
Abe, T
Ogumi, Z
[J]. JOURNAL OF POWER SOURCES, 2001, 94 (02) : 175 - 182
[8] Transmission electron microscopy (TEM) analysis of two-phase reaction in electrochemical lithium insertion within α-MoO3
Iriyama, Y
Abe, T
Inaba, M
Ogumi, Z
[J]. SOLID STATE IONICS, 2000, 135 (1-4) : 95 - 100
[9] Dilute graphite-sulfates intercalation stages studied by simultaneous application of cyclic voltammetry, probe-beam deflection, in situ resistometry, and x-ray diffraction techniques
Levi, MD
Levi, E
Gofer, Y
Aurbach, D
Vieil, E
Serose, J
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (09): : 1499 - 1508
[10] On the diffusion of Li+ defects in LiCoO2 and LiNiO2
Nakamura, K
Ohno, K
Okamura, K
Michihiro, Y
Nakabayashi, I
Kanashiro, T
[J]. SOLID STATE IONICS, 2000, 135 (1-4) : 143 - 147

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