The effect of annealing on the elastoplastic response of isotactic polypropylene

被引:33
作者
Drozdov, AD [1 ]
Christiansen, JD [1 ]
机构
[1] Univ Aalborg, Dept Prod, DK-9220 Aalborg, Denmark
关键词
isotactic polypropylene; cyclic loading; elastoplasticity; yielding; annealing;
D O I
10.1016/S0014-3057(02)00189-1
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Four series of tensile loading-unloading tests are performed on isotactic polypropylene in the sub-yield domain of deformations at room temperature. In the first series, injection-molded specimens are used as produced, whereas in the other series the samples are annealed for 24 h at 120, 140 and 160 degreesC, which covers the low-temperature region and an initial part of the high-temperature region of annealing temperatures. A constitutive model is developed for the elasto-plastic behavior of a semicrystalline polymer. The stress-strain relations are determined by five adjustable parameters that are found by fitting the experimental data. The effect of annealing is analyzed on the material constants. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:21 / 31
页数:11
相关论文
共 42 条
[1]   IN-SITU OBSERVATION OF THE PLASTIC-DEFORMATION OF POLYPROPYLENE SPHERULITES UNDER UNIAXIAL TENSION AND SIMPLE SHEAR IN THE SCANNING ELECTRON-MICROSCOPE [J].
ABOULFARAJ, M ;
GSELL, C ;
ULRICH, B ;
DAHOUN, A .
POLYMER, 1995, 36 (04) :731-742
[2]  
Al-Raheil IA, 1998, J APPL POLYM SCI, V67, P1267, DOI 10.1002/(SICI)1097-4628(19980214)67:7<1267::AID-APP16>3.0.CO
[3]  
2-Z
[4]   A morphological study of a highly structurally regular isotactic poly(propylene) fraction [J].
Alamo, RG ;
Brown, GM ;
Mandelkern, L ;
Lehtinen, A ;
Paukkeri, R .
POLYMER, 1999, 40 (14) :3933-3944
[5]   Constitutive modeling of ultra-high molecular weight polyethylene under large-deformation and cyclic loading conditions [J].
Bergström, JS ;
Kurtz, SM ;
Rimnac, CM ;
Edidin, AA .
BIOMATERIALS, 2002, 23 (11) :2329-2343
[6]   LARGE INELASTIC DEFORMATION OF GLASSY-POLYMERS .1. RATE DEPENDENT CONSTITUTIVE MODEL [J].
BOYCE, MC ;
PARKS, DM ;
ARGON, AS .
MECHANICS OF MATERIALS, 1988, 7 (01) :15-33
[7]   Scanning force microscopic investigation of plasticity and damage mechanisms in polypropylene spherulites under simple shear [J].
Coulon, G ;
Castelein, G ;
G'Sell, C .
POLYMER, 1999, 40 (01) :95-110
[8]   The effect of annealing on the time-dependent behavior of isotactic polypropylene at finite strains [J].
Drozdov, AD ;
Christiansen, JD .
POLYMER, 2002, 43 (17) :4745-4761
[9]  
DROZDOV AD, IN PRESS J APPL POLY
[10]   Second-order phase transition of high isotactic polypropylene at high temperature [J].
Gu, FM ;
Hikosaka, M ;
Toda, A ;
Ghosh, SK ;
Yamazaki, S ;
Arakaki, M ;
Yamada, K .
POLYMER, 2002, 43 (04) :1473-1481