The photoabsorption spectrum of vinylchloride (C2H3Cl) in the 8-12 eV range

被引：17

作者：

Locht, R ^{[1
]}

Leyh, B ^{[1
]}

Hottmann, K ^{[1
]}

Baumgartel, H ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST PHYS & THEORET CHEM,D-14195 BERLIN,GERMANY

来源：

CHEMICAL PHYSICS | 1997年 / 220卷 / 1-2期

关键词：

D O I：

10.1016/S0301-0104(97)00127-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photoabsorption spectrum of vinylchloride (C2H3Cl) has been measured using synchrotron radiation and has been analyzed in detail between 8.0 eV and 12.0 eV photon energy. Valence to virtual valence and Rydberg transitions have been identified and classified. Tentative assignments were based on ionization energies as measured by He(I) and threshold photoelectron spectroscopy, as reported in the joined paper [1]. Many features have been identified as being members of vibrational progressions belonging to the observed Rydberg series. (C) 1997 Elsevier Science B.V.

引用

页码：207 / 216

页数：10

共 8 条

[1]

Baer T., 1995, HIGH RESOLUTION LASE, P1

[2]

Herzberg G., 1967, MOL SPECTRA MOL STRU, V3

[3] The He(I), threshold photoelectron and constant ion state spectroscopy of vinylchloride (C2H3Cl) [J].

Locht, R ;

Leyh, B ;

Hottmann, K ;

Baumgartel, H .

CHEMICAL PHYSICS, 1997, 220 (1-2) :217-232

[4]

Ng C. Y., 1991, VACUUM ULTRAVIOLET P, P169

[5]

REINKE D, 1973, Z NATURFORSCH A, V28, P1021

[6] ABSORPTION AND IONIZATION COEFFICIENTS OF VINYL CHLORIDE [J].

SOOD, SP ;

WATANABE, K .

JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (08) :2913-&

[7] EXCITATION AND IONIZATION OF THE MONOHALOETHYLENES (C2H3X,X=F,CL,BR,I) .2. PHOTOIONIZATION BY HE(I) AND HE(II) PHOTOELECTRON-SPECTROSCOPY AND VALENCE-SHELL EXCITATION BY ELECTRON-ENERGY LOSS SPECTROSCOPY [J].

SZE, KH ;

BRION, CE ;

KATRIB, A ;

ELISSA, B .

CHEMICAL PHYSICS, 1989, 137 (1-3) :369-390

[8] THE VACUUM ULTRAVIOLET PHOTOABSORPTION AND PHOTOELECTRON-SPECTROSCOPY OF FLUOROCHLOROETHENES - THE 1,1-C2H2FCL, CIS-C2H2FCL AND TRANS-C2H2FCL [J].

TORNOW, G ;

LOCHT, R ;

KAUFEL, R ;

BAUMGARTEL, H ;

JOCHIMS, HW .

CHEMICAL PHYSICS, 1990, 146 (1-2) :115-128

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