Electrochemical reduction of some methanofullerenes. On the mechanism of the retro-Bingel reaction

被引：17

作者：

Nuretdinov, IA ^{[1
]}

Yanilkin, VV ^{[1
]}

Gubskaya, VP ^{[1
]}

Maksimyuk, NI ^{[1
]}

Berezhnaya, LS ^{[1
]}

机构：

[1] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2000年 / 49卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

phosphonomethanofullerene; electrochemical reduction; Bingel reaction; retro-Bingel reaction;

D O I：

10.1007/BF02494770

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of electrochemical reduction of methanofullerenes bearing phosphonate and alkoxycarbonyl groups at the exo-carbon atom were studied. The mechanism of the retro-Bingel reaction as the cleavage of two C-C bonds between the C(61) atom and the fullerene shell accompanied by electrochemical electron transfer was proposed.

引用

页码：427 / 430

页数：4

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