X-ray absorption spectroscopic studies on light-induced excited spin state trapping of an Fe(II) complex

被引：68

作者：

Lee, JJ

Sheu, HS

Lee, CR

Chen, JM

Lee, JF

Wang, CC

Huang, CH

Wang, Y ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 10764, Taiwan

[2] Synchrotron Radiat Res Ctr, Hsinchu, Taiwan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2000年 / 122卷 / 24期

关键词：

D O I：

10.1021/ja9943290

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Light-induced excited spin state trapping of Fe(phen)(2)(NCS)(2) is studied by X-ray absorption spectroscopy using synchrotron radiation. The molecular structure of the excited high-spin state at 17 K is investigated by EXAFS. The relaxation of the light-induced high-spin state at various temperatures is monitored through the absorption spectra. The concurrent abrupt lattice change with the change in electronic configuration is observed through single crystal X-ray diffraction. The lattice cooperative effect is important in the relaxation behavior. The magnetic property and the relaxation behavior of two differently prepared samples are distinctly different.

引用

页码：5742 / 5747

页数：6

共 40 条

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[2]

ASAKURA A, 1996, XRAY ABSORPTION FINE, P34

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