Coherent excited state intramolecular proton transfer probed by time-resolved fluorescence

被引：102

作者：

Kim, Chul Hoon ^{[1
]}

Joo, Taiha ^{[1
]}

机构：

[1] Pohang Univ Sci & Technol, Dept Chem, Pohang, South Korea

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2009年 / 11卷 / 44期

基金：

新加坡国家研究基金会;

关键词：

TRANSFER-REACTION DYNAMICS; SPECTROSCOPY; 2-(2'-HYDROXYPHENYL)BENZOTHIAZOLE; LUMINESCENCE; RELAXATION; MOLECULES; MECHANISM; MOTION; ESIPT;

D O I：

10.1039/b915768a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An ultra-fast chemical reaction can act as an impulsive excitation of the vibrations. Excited state intramolecular proton transfer in 10-hydroxybenzo[h]quinoline proceeds in 13 fs. As a result, product vibrational modes with their periods longer than (13 x 2) fs are coherently excited in the product potential surface, which can be observed most unambiguously by the oscillations in the time-resolved fluorescence signal of the product keto isomer.

引用

页码：10266 / 10269

页数：4

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