Syntheses of fluorescence-labeled artificial leaf-opening substances, fluorescent probe compounds useful for bioorganic studies of nyctinasty

被引:8
作者
Ueda, M [1 ]
Sawai, Y [1 ]
Yamamura, S [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Yokohama, Kanagawa 2238522, Japan
关键词
plants; natural products; biologically active compounds; fluorescent probe;
D O I
10.1016/S0040-4039(00)00394-4
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In a previous paper, the syntheses of potassium galactolespedezate (1) and potassium galactoisolespedezate (2), artificial leaf-opening substances useful for bioorganic studies of nyctinasty were reported. The fluorescent probe compounds, fluorescence-labeled galactoisolespedezates (3, 10, 13), designed on the basis of 1 and 2, were prepared. In particular, compound 3 was bioactive at 5 X 10(-5) M, one-fiftieth as strong as the natural leaf-opening substance. This fluorescent probe would be useful for bioorganic studies of nyctinasty. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3433 / 3436
页数:4
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