High-yield liquid-phase oxygenation of methane with hydrogen peroxide catalyzed by 12-molybdovanadophosphoric acid catalyst precursor

被引：26

作者：

Seki, Y ^{[1
]}

Mizuno, N ^{[1
]}

Misono, M ^{[1
]}

机构：

[1] UNIV TOKYO,GRAD SCH ENGN,DEPT APPL CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

APPLIED CATALYSIS A-GENERAL | 1997年 / 158卷 / 1-2期

关键词：

methane; selective oxygenation; hydrogen peroxide; heteropolyacid;

D O I：

10.1016/S0926-860X(97)00177-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The title reaction was most efficiently catalyzed by H4PVMo11O40 catalyst precursor in (CF3CO)(2)O solvent at 353 K. A conversion to the oxygenates such as methylformate and formic acid of 33.0% was achieved.

引用

页码：L47 / L51

页数：5

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