Preparation of hyperbranched polyacrylates by atom transfer radical polymerization .3. Effect of reaction conditions on the self-condensing vinyl polymerization of 2-((2-bromopropionyl)oxy)ethyl acrylate

被引：173

作者：

Matyjaszewski, K

Gaynor, SG

机构：

[1] Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh

来源：

MACROMOLECULES | 1997年 / 30卷 / 23期

关键词：

D O I：

10.1021/ma970635r

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The homopolymerization of 2-(2-bromopropionyl)oxy)ethyl acrylate (BPEA) by atom transfer radical polymerization (ATRP), a ''living''/controlled radical polymerization system, has yielded a hyperbranched polymer. Variation of the reaction conditions and especially the concentration of copper(II) in the polymerization system affects not only the rate of polymerization but also the chain architecture. The copper(II) concentration in the polymerization medium is affected by solvent, the ligand used to complex copper, and temperature. The effects of temperature and ligand on the polymerization rate and the resulting chain architecture were studied.

引用

页码：7042 / 7049

页数：8

共 35 条

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