CuBr/rac-BINOL-catalyzed N-arylations of aliphatic amines at room temperature

被引：165

作者：

Jiang, Deshou

Fu, Hua ^{[1
]}

jiang, Yuyang

Zhao, Yufen

机构：

[1] Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Bioorgan Phosphorous Chem & Chem Biol, Beijing 100084, Peoples R China

[2] Tsing Hua Univ, Grad Sch Shenzhen, Key Lab Chem Biol, Shenzhen 518057, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 02期

关键词：

D O I：

10.1021/jo062060e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We have developed an efficient and readily available catalyst system CuBr/racemic BINOL (1,1'-binaphthyl-2,2'-diol) that catalyzes N-arylation of aliphatic amines at room temperature, and this inexpensive catalyst system is of high selectivity and tolerance toward various functional groups in the substrates.

引用

页码：672 / 674

页数：3

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