Charge separation in confined charged fluids

被引:32
作者
Yu, J [1 ]
Degreve, L [1 ]
LozadaCassou, M [1 ]
机构
[1] UNIV SAO PAULO,FAC FILOSOFIA CIENCIAS & LETRAS,RIBEIRAO PRET,SP,BRAZIL
关键词
D O I
10.1103/PhysRevLett.79.3656
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
A charge segregation phase is found in a charged fluid confined by a charged spherical pore: The negative ions are completely separated from a spherical core comprised of only positive ions. Within the segregation regime, there is a region for which the pressure decreases with increasing fluid confinement. [S0031-9007(97)04362-7].
引用
收藏
页码:3656 / 3659
页数:4
相关论文
共 20 条
  • [1] ALEJANDRE J, 1996, MOL PHYS, V88, P1317
  • [2] MONTE-CARLO AND HNC/MSA RESULTS FOR AN ASYMMETRICAL ELECTROLYTE IN AN EXTERNAL ELECTRICAL-FIELD OF SPHERICAL GEOMETRY
    DEGREVE, L
    LOZADACASSOU, M
    [J]. MOLECULAR PHYSICS, 1995, 86 (04) : 759 - 768
  • [3] THERMODYNAMICS AND STRUCTURE OF THE PRIMITIVE MODEL NEAR ITS GAS-LIQUID TRANSITION
    GONZALEZTOVAR, E
    LOZADACASSOU, M
    MIERYTERAN, L
    MEDINANOYOLA, M
    [J]. JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (09) : 6784 - 6791
  • [4] THE SPHERICAL DOUBLE-LAYER - A HYPERNETTED CHAIN MEAN SPHERICAL APPROXIMATION CALCULATION FOR A MODEL SPHERICAL COLLOID PARTICLE
    GONZALEZTOVAR, E
    LOZADACASSOU, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (09) : 3761 - 3768
  • [5] Hoppe W., 1983, BIOPHYSICS
  • [6] FORCES BETWEEN SURFACES IN LIQUIDS
    ISRAELACHVILI, JN
    MCGUIGGAN, PM
    [J]. SCIENCE, 1988, 241 (4867) : 795 - 800
  • [7] ISRAELACHVILI JN, 1985, PHYSICS AMPHIPHILES
  • [8] Lozada-Cassou M., 1992, FUNDAMENTALS INHOMOG
  • [9] Correlation of charged fluids separated by a wall of finite thickness: Dependence on the charge of the fluid and the wall
    LozadaCassou, M
    Yu, J
    [J]. PHYSICAL REVIEW E, 1997, 56 (03): : 2958 - 2965
  • [10] Violation of the electroneutrality condition in confined charged fluids
    LozadaCassou, M
    Olivares, W
    Sulbaran, B
    [J]. PHYSICAL REVIEW E, 1996, 53 (01): : 522 - 530