Using soluble polymers to recover catalysts and ligands

被引:515
作者
Bergbreiter, DE [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
关键词
D O I
10.1021/cr010343v
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The separation methods used to recover soluble polymeric ligands or soluble polymer-ligated homogeneous catalysts were discussed. Many approaches existed for batch and continuous recycling of soluble polymer-bound catalysts. Soluble polymer-supported catalysts have advantages of more facile characterization and very predictable reactivity. Results showed that extra synthetic work was necessary to immobilize a catalyst or to prepare the requisite ligands.
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页码:3345 / 3383
页数:39
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