Self-assembling poly(dioxaborole)s as blue-emissive materials

被引：91

作者：

Niu, Weijun ^{[1
]}

Smith, Mark D. ^{[1
]}

Lavigne, John J. ^{[1
]}

机构：

[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 51期

关键词：

D O I：

10.1021/ja065986c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conjugated, borole-linked polymers have been self-assembled based on boronate ester formation between a fluorene-2,7-diboronic acid and 1,2,4,5-tetrahydroxybenzene. Readily soluble polymers with molecular weights approaching 60000 have been generated with materials exhibiting extended conjugation over approximately 3-5 borole linkages. Emission from these polymers reaches into the visible (blue) range, representing a novel class of blue-emitting materials. Copyright © 2006 American Chemical Society.

引用

页码：16466 / 16467

页数：2

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