Rectangular grid two-dimensional sheets of copper(II) bridged by both co-ordinated and hydrogen bonded 4,4'-bipyridine (4,4'-bipy) in [Cu(mu-4,4'-bipy)(H2O)(2)(FBF3)(2)]center dot 4,4'-bipy

被引:211
作者
Blake, AJ [1 ]
Hill, SJ [1 ]
Hubberstey, P [1 ]
Li, WS [1 ]
机构
[1] UNIV NOTTINGHAM, DEPT CHEM, NOTTINGHAM NG7 2RD, ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 06期
关键词
D O I
10.1039/a700036g
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complex [Cu(mu-4,4'-bipy)(H2O)(2)(FBF3)(2) . 4,4'-bipy(4,4'-bipy = 4,4'-bipyridine), in which copper atoms are linked by Cu-4,4'-bipy-Cu and Cu-OH2 ... 4,4'-bipy ... H2O-Cu assemblies, involving co-ordinated and hydrogen bonded 4,4'-bipy, respectively, to form two-dimensional rectangular grid sheets, has been isolated and structurally characterised.
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页码:913 / 914
页数:2
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