Structure of trans-diisothiocyanato(ethoxo)oxo-bis(triphenylphosphine)rhenium(V) complex

被引：6

作者：

Battistuzzi, R ^{[1
]}

Saladini, M ^{[1
]}

机构：

[1] Univ Modena & Reggio Emilia, Dept Chem, I-41100 Modena, Italy

来源：

INORGANICA CHIMICA ACTA | 2000年 / 304卷 / 01期

关键词：

crystal structures; rhenium complexes; oxo-ethoxo complexes; isothiocyanato complexes;

D O I：

10.1016/S0020-1693(00)00057-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compound consists of [ReO(NCS)(2)(OEt)(PPh3)(2)] units in which the rhenium(V) center shows a slightly distorted octahedral coordination. The two N-coordinated NCS- groups are trans to each other, as the Re=O and the Re-Oft units. The Re=O and Re-OEt bond lengths [1.682(10) and 1.871(10) Angstrom, respectively] and the geometry about the ethoxide oxygen atom indicate that in both cases M-O ligation has a considerable degree of multiple bond. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：114 / 117

页数：4

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