Magnetic exchange coupling tunable by means of selective cation binding into poly(radical-armed) azacrowns

被引：12

作者：

Igarashi, Kazuki

Nogami, Takashi

Ishida, Takayuki ^{[1
]}

机构：

[1] Univ Electrocommun, Dept Appl Phys & Chem, Chofu, Tokyo 1828585, Japan

[2] Univ Electrocommun, Course Coherent Opt Sci, Chofu, Tokyo 1828585, Japan

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 05期

关键词：

D O I：

10.1039/b613637k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Host - guest complexes of tris(NN - CH2)-substituted 1,4,7-triazacyclononane and tetrakis( NN - CH2)- substituted 1,4,7,10-tetraazacyclododecane afforded the folded structures of the hosts where the NN radical oxygen atoms were coordinated to the guest metal ion, leading to enhanced antiferromagnetic couplings in the solid state and an ESR line broadening in the solution phase (NN = 4,4,5,5-tetramethylimidazolin-1-oxyl 3-oxide).

引用

收藏

页码：501 / 503

页数：3

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