Formation of diamond from supercritical H2O-CO2 fluid at high pressure and high temperature

被引:44
作者
Kumar, MDS
Akaishi, M
Yamaoka, S
机构
[1] NIRIM, Tsukuba, Ibaraki 3050044, Japan
[2] NIRIM, Japan Sci & Technol Corp, Core Res Evolut Sci & Technol, Tsukuba, Ibaraki, Japan
关键词
formation of diamond; high pressure and high temperature; H2O-CO2 supercritical fluid;
D O I
10.1016/S0022-0248(00)00352-3
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Formation of diamond was studied from the starting graphite and anhydrous oxalic acid (COOH)(2) in a platinum-sealed capsule at 7.7 GPa and 1300-1500 degrees C. Small octahedral diamond crystals < 10 mu m in size were crystallized and the fluid phase in coexistence with diamonds was found to be composed of H2O and CO2 by a mass spectrometer. Besides, when C-13 graphite was used as a starting material, (CO2)-C-13 was present with (CO2)-C-12 in the fluid, showing that a H2O-CO2 fluid was first formed by the decomposition of the oxalic acid, and then graphite dissolved into the fluid and precipitated as diamond. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:203 / 206
页数:4
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