Synthesis and electrochemical properties of fullerene-rich nanoclusters synthesized by cobalt-catalyzed cyclotrimerization of bis(aryl)alkyne fullerodendrimers

被引：45

作者：

Hahn, Uwe

Maisonhaute, Emmanuel

Amatore, Christian

Nierengarten, Jean-Francois

机构：

[1] Univ Paris 06, UMR CNRS Pasteur 8640, Ecole Normale Super, Dept Chem, F-75231 Paris 05, France

[2] CNRS, Chim Coordinat Lab, Grp Chim Fullerenes & Syst Conjugues, F-31077 Toulouse, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 06期

关键词：

cyclic voltammetry; dendrimers; electrochemistry; fullerenes;

D O I：

10.1002/anie.200603765

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A lot of balls: Up to 24 C60 units were assembled around a hexaphenylbenzene core by cobalt-catalyzed cyclotrimerization of bis(aryl)alkyne fullerodendrimers (see scheme). Electrochemical investigations reveal that interactions between C60 units within a single dendrimer molecule are extremely efficient. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：951 / 954

页数：4

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