A novel pulse isotopic exchange technique for rapid determination of the oxygen surface exchange rate of oxide ion conductors

被引：128

作者：

Bouwmeester, Henny J. M. ^{[1
]}

Song, Chunlin

Zhu, Jianjun

Yi, Jianxin

Annaland, Martin van Sint

Boukamp, Bernard A.

机构：

[1] Univ Twente, Fac Sci & Technol, MESA Inst Nanotechnol, NL-7500 AE Enschede, Netherlands

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2009年 / 11卷 / 42期

关键词：

FUEL-CELL; SELF-DIFFUSION; CATALYSTS; KINETICS; SIMS; TRANSPORT;

D O I：

10.1039/b912712g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We demonstrate the use of a novel pulse (18)O-(16)O isotopic exchange technique for the rapid determination of the oxygen surface exchange rate of oxide ion conductors while simultaneously providing insight into the mechanism of the oxygen exchange reaction, which contributes to the efficient development of devices incorporating these solids, such as solid oxide fuel cells and oxygen transport membranes.

引用

页码：9640 / 9643

页数：4

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