Redox supercapacitor using polyaniline doped with Li salt as electrode

被引:99
作者
Ryu, KS [1 ]
Kim, KM [1 ]
Park, YJ [1 ]
Park, NG [1 ]
Kang, MG [1 ]
Chang, SH [1 ]
机构
[1] Elect & Telecommun Res Inst, Battery Technol Team, Taejon 305350, South Korea
关键词
supercapacitor; redoxcapacitor; conducting polymer; polyaniline; Li salt doping;
D O I
10.1016/S0167-2738(02)00386-7
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We prepared polyaniline powder doped with LiPF6 and utilized it as an electrode material in a polymer redox supercapacitor. The electrode sheet was fabricated by coating the slurry directly on a charge collector. We also compared the performance of porous polyolefin separator as supplied and the polymer electrolyte as prepared. The redox supercapacitor using the polyolefin separator exhibits similar to 100 F/g specific capacitance at the initial discharge and retains similar to 70 F/g after 5000 cycles, while the initial specific capacitance using the polymer electrolyte is similar to 80 F/g and retains similar to 60 F/g after 5000 cycles, (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:861 / 866
页数:6
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