Magnetic effect on the phase transitions of n-C32H66 measured by high resolution and super-sensitive DSC

被引：11

作者：

Inaba, H

Tozaki, K

Hayashi, H

Quan, CJ

Nemoto, N

Kimura, T

机构：

[1] Chiba Univ, Fac Educ, Dept Sci Educ, Inage Ku, Chiba 2638522, Japan

[2] Kyushu Univ, IGSES, Dept Mol & Mat Sci, Hakozaki, Fukuoka 8128581, Japan

[3] Tokyo Metropolitan Univ, Fac Technol, Hachioji, Tokyo 1920397, Japan

来源：

PHYSICA B-CONDENSED MATTER | 2002年 / 324卷 / 1-4期

基金：

日本学术振兴会;

关键词：

DSC; n-alkane; phase transition; magnetic effect; refrigerator-cooled superconducting magnet;

D O I：

10.1016/S0921-4526(02)01274-7

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

A high-resolution and super-sensitive DSC measurable under strong magnetic field has been constructed in the magnetic bore of a refrigerator-cooled superconducting magnet. The baseline stability of the calorimeter was about 20 nW. The magnetic effect to the phase transitions of n-C32H66 was measured using the calorimeter. The transition temperatures due to solid-solid transition and due to melting were shifted to higher temperatures by several tens of mK by applying the field of 5 T. The temperature shift due to the magnetic orientation was discussed based on the extension of the Clapeyron equation. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：63 / 71

页数：9

共 24 条

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