Advanced liquid chromatographymass spectrometry (LC-MS) methods applied to wastewater removal and the fate of surfactants in the environment

被引：78

作者：

Gonzalez, Susana ^{[1
]}

Petrovic, Mira ^{[1
]}

Barcelo, Damia ^{[1
]}

机构：

[1] CSIC, IIQAB, Dept Environm Chem, ES-08034 Barcelona, Spain

来源：

TRAC-TRENDS IN ANALYTICAL CHEMISTRY | 2007年 / 26卷 / 02期

关键词：

advanced treatment; LC; LC-MS2; liquid chromatography; mass spectrometry; MS; surfactant; tandem mass spectrometry; wastewater treatment;

D O I：

10.1016/j.trac.2006.12.003

中图分类号：

O65 [分析化学];

学科分类号：

070302 [分析化学]; 081704 [应用化学];

摘要：

This article is an overview of current methodologies for the analysis of different classes of surfactants by advanced liquid chromatography-mass spectrometry (LC-MS) technologies, including LC-tandem MS (LC-MS2), ion trap, quadrupole-time-of-flight (Q-TOF) and matrix-assisted laser desorption/ionization (MALDI)-TOF. It also discusses the application of LC-MS methods in studies of the fate and the behavior of surfactants during wastewater treatment either using conventional activated sludge (CAS), membrane bioreactor (MBR) or advanced oxidation processes (AOP's). Using advanced LC-MS methodologies, it is possible to detect a variety of polar metabolites, such as carboxylic acids and short-chain sulphonic-acid derivatives of surfactants formed during the biodegradation processes in either the wastewater-treatment plants or the environment. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：116 / 124

页数：9

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